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Table of contents
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Table of contents

0:00
Что изучим и что научимся решать?
0:41
Аморфные и кристаллические вещества
1:41
Кристаллическая решетка
2:14
Виды кристаллических решеток
3:38
Металлическая кристаллическая решетка
6:14
Ионная кристаллическая решетка
11:08
Атомная кристаллическая решетка
15:18
Молекулярная кристаллическая решетка
18:19
1. На что важно обратить внимание?
18:43
2. На что важно обратить внимание?
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химия 11 класс
богдан чагин
анастасия майер
химия 10 класс
добротина
добротина егэ
добротина егэ 2023
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решу егэ
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кристаллические решетки
заучить или понять за 20 минут?
разбор варианта
умскул_химия
анастасиямайер
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  • ruRussian
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00:00:08
Hello everyone My name is Anastasia Mayer I
00:00:11
am a chemistry teacher at the
00:00:12
online school Umskul and specifically in this
00:00:14
video we will discuss such a topic
00:00:16
as crystal lattices and at the same time
00:00:18
learn how to solve the fourth task of the Unified State Exam
00:00:21
dedicated to this topic Before we
00:00:23
begin I would like to clarify what is in the description To
00:00:25
this video I also added links to
00:00:27
previous videos of a similar format.
00:00:29
Therefore, if you don’t want to memorize
00:00:31
chemistry but really understand this subject,
00:00:33
be sure to follow the links in
00:00:35
the description of this video and watch the
00:00:37
previous videos to pass the Unified State Exam with
00:00:40
high scores, first let’s clarify
00:00:42
with you that everything substances can, in principle, be
00:00:44
divided into two large categories:
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amorphous substances and
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crystalline substances, amorphous substances are
00:00:50
those that essentially do not have a
00:00:53
definite structure; the particles in them
00:00:55
have a clear order, one
00:00:58
particle there, another here, a third one a
00:01:00
kilometer away from them, and because of this
00:01:02
chaos in the arrangement of particles,
00:01:04
amorphous compounds do not have any
00:01:06
clear temperatures and other clear
00:01:09
tabular indicators, another
00:01:12
thing is that these substances are crystalline, in
00:01:13
fact, they are their complete opposite
00:01:15
because in crystalline substances
00:01:17
each particle has its own place,
00:01:19
you feel there is a certain structure in the
00:01:22
arrangement of particles there is a clear order
00:01:25
thanks to this clear order,
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crystalline substances
00:01:30
have clear melting points and
00:01:32
other tabular indicators. Today we
00:01:35
will talk to you in the
00:01:36
fourth task of the Unified State Exam specifically about
00:01:38
crystalline substances, as we
00:01:41
told you earlier in crystalline
00:01:43
substances we observe absolute
00:01:45
order in the arrangement of particles each
00:01:47
particle has its own place, essentially this
00:01:50
very order in the arrangement of particles is
00:01:52
called a crystal lattice
00:01:54
again Let's say what it is, essentially a
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crystal lattice is a
00:01:58
spatial frame in which the
00:02:00
particles are located, a crystal
00:02:03
lattice essentially shows us how these
00:02:05
particles are located in a crystal
00:02:08
and accordingly the very places in which
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these very particles are located are called
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nodes of the crystal lattice because
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what particles we have are located at the nodes of
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our crystal lattice and
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there are four types in total. So let’s look at
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each of them first simply by
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name So the types of crystal
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lattices
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the first is actually a metal
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crystal lattice
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the second the type of crystal lattices is
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ionic
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[music] the
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third atomic
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and the fourth type of crystal lattices
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is the molecular crystal lattice
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[music]
00:02:53
I think, in principle, from the names of the
00:02:55
crystal lattices it is clear what is
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located in their nodes, for example, in the
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nodes of the ionic crystal lattice
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there are ions of charged particles
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located in the atomic nodes atoms And in the
00:03:05
nodes of the molecular, respectively,
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the molecule, here’s a small spoiler
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in advance So what do you and I need to
00:03:12
know about each of the types of
00:03:13
crystal lattice, but the first thing is
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that we have already said what is located in the nodes of
00:03:17
each crystal lattice, this is as
00:03:20
we understand it is clear from its name the second
00:03:22
This is what substances this
00:03:24
type of crystal lattice is characteristic of. And the third,
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accordingly, is what
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physical and some chemical properties
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do substances with this type of
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crystal lattice have, but
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we’ll talk about everything in more detail now.
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So the first type of
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crystal lattice, as I said, is
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metallic crystalline lattice
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as It is clear from its name that the nodes
00:03:46
contain particles such as atoms and
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metal ions. Let’s immediately write down
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what properties will be characteristic of
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all substances that have a
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metal crystal lattice,
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that is, for metals. Let’s remember
00:04:03
for this purpose any
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average metal. Well, first of all
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metals are usually solid substances
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in their state of aggregation, the
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only exception is mercury, which is liquid under
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normal conditions, let’s write this down right away, that
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is, the first property is a
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solid state of aggregation,
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the second, respectively, their general properties.
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We can remember from
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personal experience. Probably each of you at
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some point for example, I fried myself some eggs
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and then accidentally touched the
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frying pan in which all this happened
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here and you can accordingly remember the
00:04:40
second property, as I already said, this is
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that metals are excellent conductors of heat and
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they are also excellent conductors of electricity, but
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let us check this from personal
00:04:49
experience Let’s not So, the second
00:04:52
property of substances with a metal
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crystal lattice is good
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heat and electrical conductivity. The
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following property that we can
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remember regarding metals is,
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accordingly, that they
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can melt at a certain heating
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and subsequently
00:05:18
we can give the necessary
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form which they will retain, this
00:05:23
property is called plasticity or
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malleability in this case, you can, for example,
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remember the same Blacksmiths who
00:05:29
forged various devices from metal and other metals,
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that is, we
00:05:35
heat the metal. Yes, it melts or
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becomes softer, more pliable,
00:05:40
and with the help of this we can give it the
00:05:42
specific shape we need.
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subsequently will retain this and
00:05:47
is called plasticity or malleability,
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we will write this also in
00:05:56
this way common to all metals,
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that is, substances with a metal
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crystal lattice are
00:06:02
solid state of aggregation, with the exception of
00:06:05
as we said here, mercury is liquid under
00:06:07
normal conditions, good
00:06:09
conductivity of heat and electricity, that is,
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good heat and electrical conductivity and
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plasticity or malleability, the
00:06:16
next type of crystal lattice is an
00:06:18
ionic crystal lattice, as I
00:06:21
think. It is clear from the name that its nodes
00:06:23
contain particles such as
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positively charged or negatively
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charged ions.
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For what substances will an ionic crystal
00:06:32
lattice be characteristic absolutely
00:06:34
logically, and for substances that
00:06:36
contain there are ionic bonds, let me
00:06:38
remind you a little about the topic of
00:06:41
chemical bonds, ionic bonds are
00:06:42
usually realized between a metal and a
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non-metal by the opposites plus and
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minus, relatively speaking, for example, they are a
00:06:49
compound sodium chlorine, we see a bond with a
00:06:51
metal non-metal potassium 2co3 barium o
00:06:55
lithium OH and others, that is, metal-
00:06:58
nonmetal bonds and sinful chemistry in our country
00:07:00
are always ionic. And if there are
00:07:03
ionic bonds in a compound, then this is a connection of an
00:07:05
ionic structure with an ionic crystal
00:07:07
lattice. That is, everything is completely
00:07:09
interconnected. I also remind you that
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ionic bonds also exist in
00:07:13
ammonium compounds, that is, particles of nh4 + and
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its various analogues in organic
00:07:19
chemistry we summarize with you in this way
00:07:22
For what substances will an
00:07:24
ionic crystal lattice be characteristic? It will be
00:07:26
characteristic for substances in which
00:07:29
ionic bonds are used, most often
00:07:31
a metal or a non-metal, that is, for various
00:07:33
salts of metal oxides and hydroxides and
00:07:36
ammonium compounds of its analogous
00:07:39
substances in organic chemistry. What are the
00:07:41
properties of what? the most interesting things will be
00:07:43
characteristic of substances with this type of
00:07:45
crystal lattice. Well, let’s
00:07:47
remember
00:07:49
the average statistical salt. Yes, for example, the
00:07:51
same sodium chlorine is table
00:07:54
salt that each of us has
00:07:56
in the kitchen, what can we say about it?
00:07:57
Well, first of all, this substance
00:08:01
table salt, solid in its state of aggregation, we will write down
00:08:05
further. Next, what we can say for sure is
00:08:07
that this compound is soluble in water.
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For example, we can immediately recall how we
00:08:12
cook dumplings or pasta and
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accordingly throw that
00:08:17
same ill-fated sodium chloride,
00:08:20
sodium chloride, table salt into boiling water; it
00:08:21
dissolves perfectly in water, therefore, the second
00:08:24
property that we will write down for
00:08:26
substances with an ionic crystal
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lattice is good solubility in
00:08:30
water, not all substances with such a
00:08:32
crystal lattice are well
00:08:33
soluble in water, but many are the
00:08:39
following property that again
00:08:41
may come to your mind. Perhaps this is
00:08:45
that solutions and melts these substances
00:08:47
conduct electric current very well,
00:08:50
I can give an example from life that
00:08:54
some people have probably encountered, if we
00:08:56
take two vessels with water, but
00:08:59
one water will be ordinary and the second will be
00:09:01
salty, that is, the one in which they threw
00:09:04
salt, for example table salt,
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then the salty water will be much it is better
00:09:09
to conduct electricity precisely
00:09:11
because of the presence of charged particles
00:09:13
of ions, respectively, the third properties
00:09:16
that we will write down for substances with an
00:09:17
ionic crystal lattice is
00:09:20
precisely the fact that their solutions and melts
00:09:23
conduct electric current well
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[music]
00:09:31
what other interesting things can you
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remember here for example, this is such a property of
00:09:35
table salt as refractoriness, that
00:09:38
is, this substance table salt has a
00:09:40
very high melting point, in
00:09:43
my opinion, about 800 degrees, if my
00:09:46
memory serves me correctly, that is, at this
00:09:47
temperature table salt turns into a
00:09:50
liquid state of aggregation, melts, that
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is, melts at a very high
00:09:54
temperature it melts hard, therefore, a
00:09:57
compound of this kind is called
00:09:59
refractory and the compound is quite
00:10:01
strong, respectively. The
00:10:05
fourth property that we
00:10:07
will write down in this way is strength and the
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fifth is refractory.
00:10:12
That is, as a rule, such
00:10:14
substances have high
00:10:18
melting points; they are really difficult
00:10:20
to melt. So let's summarize everything
00:10:22
that we are here with you wrote an ionic
00:10:25
crystal lattice at the nodes of such a
00:10:27
crystal lattice it is absolutely
00:10:28
logical that ions are located as It is clear from
00:10:31
the name that this type of
00:10:33
crystal lattice is typical for substances with
00:10:34
ionic bonds inside, most often these are
00:10:37
bonds metal non-metal sodium chlorine Potassium
00:10:40
2co3 bario Lithium OH and so on yes Or
00:10:44
for the compound of ammonium and its some
00:10:46
similar substances in organic chemistry
00:10:48
what properties are characteristic of these
00:10:50
compounds this is usually a
00:10:52
solid state of aggregation Yes under
00:10:54
normal conditions this is good as a
00:10:56
rule solubility in water
00:10:58
conduction of electricity in solutions or
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melts due to the fact that they
00:11:04
disintegrate there into ions plus and minus
00:11:06
strength and refractoriness
00:11:08
So, the penultimate type of
00:11:10
crystal lattice for today is the atomic
00:11:12
crystal lattice as It is clear from
00:11:15
the name that its nodes contain
00:11:16
particles such as atoms. Let's immediately write down
00:11:21
what substances have this type of
00:11:24
structure; in fact, the list of these substances
00:11:26
for the Unified State Exam is actually not that long and
00:11:29
the easiest way to actually remember them
00:11:31
is that substances with an atomic
00:11:33
crystal lattice include
00:11:35
carbon in the form of graphite or diamond,
00:11:37
silicon and many of its compounds,
00:11:39
for example, silicon oxide and silicon carbide.
00:11:42
Boron and red black phosphorus; the list is
00:11:46
quite small and can be found in the Unified State Examination
00:11:48
just what I wrote
00:11:50
right here are what properties
00:11:54
do substances with an
00:11:56
atomic crystal lattice have in common with each other;
00:11:57
respectively, the atoms that are located at the
00:12:00
nodes of these crystal lattices are
00:12:02
connected to each other by extremely strong
00:12:05
bonds, which explains
00:12:08
many of the physical and chemical properties of
00:12:10
these substances, I propose you can sort them out
00:12:13
using the example of the same Diamond, a diamond.
00:12:16
It is hard under normal conditions,
00:12:17
super strong and a super refractory
00:12:21
combination. Yes, Diamond is so strong
00:12:23
that it can even cut glass; it is
00:12:28
so refractory that it melts
00:12:30
only at a temperature of 3.5 to 4,
00:12:33
approximately thousand degrees. Based on from this
00:12:36
we can formulate with you the first three
00:12:38
properties which, in principle, are characteristic
00:12:41
of most substances with an atomic
00:12:43
crystal lattice. The first is that
00:12:46
our substances are solid, as we have already said,
00:12:49
in terms of their state of aggregation,
00:12:52
strong, we immediately remember Diamond
00:12:56
and refractory, that is, it melts at very
00:12:59
high temperatures to really melt them
00:13:02
heavily
00:13:03
refractory, what can we remember, well,
00:13:08
actually, Diamond practically does not
00:13:11
conduct electric current for us, this is the fourth
00:13:13
property and one more thing. You can also say that
00:13:16
these are all substances that are quite chemically
00:13:19
inert, that is, it is really very difficult to make them interact with someone
00:13:24
even if you have
00:13:26
a diamond ring and you
00:13:29
respectively lower your hand with a diamond
00:13:31
ring
00:13:32
into a solution of concentrated sulfuric
00:13:34
acid with Diamond, believe me, nothing
00:13:37
will happen to the prophet, we are now, of course,
00:13:39
keeping silent about this is another question, but as a fact
00:13:41
nothing will happen to Diamond. This
00:13:43
substance is extremely chemically lazy and
00:13:46
inert to make it react with someone
00:13:48
It’s difficult to
00:13:50
formulate the fourth and fifth properties accordingly
00:13:52
based on what we said. The
00:13:54
fourth property, as a rule, These
00:13:57
substances do not conduct electric current well,
00:14:01
and the fifth property is chemical
00:14:03
inertness, laziness, inactivity,
00:14:08
probably in fact, based
00:14:10
on these first three of the
00:14:13
four types of crystal lattices, you
00:14:15
already understand that properties can be learned by heart it is not
00:14:19
necessary to understand the properties that
00:14:21
will be characteristic of substances with some kind of
00:14:24
crystal lattice, metallic,
00:14:26
atomic, ionic, molecular;
00:14:28
it is enough to simply recall one
00:14:30
bright representative, for example, in the case of a
00:14:33
metallic crystal lattice,
00:14:35
you can recall the metal and formulate the
00:14:37
basic properties from there in order to
00:14:39
formulate the
00:14:41
properties accordingly substances with an ionic crystal
00:14:43
lattice, it is enough to remember
00:14:45
some compound With ionic
00:14:47
bonds The same table salt
00:14:48
sodium chlorine to formulate all these
00:14:52
properties We also did not have to
00:14:54
include any
00:14:57
new neural connections and so on, we
00:15:00
just had to Remember everything that
00:15:03
we know based on personal experience about
00:15:05
such a compound as diamond, that is, there is
00:15:07
no need to voice the properties in any case;
00:15:10
remember some prominent
00:15:12
representative who has this
00:15:14
type of crystal lattice and
00:15:16
independently deduce for yourself all the
00:15:18
necessary properties. Well, the last type of
00:15:21
crystal lattice is a molecular
00:15:23
crystal lattice, as I think you
00:15:25
understand from the name that its nodes
00:15:26
contain particles such as molecules.
00:15:29
Moreover, they are connected by fairly weak
00:15:32
intermolecular interactions, which
00:15:35
largely explains their chemical and
00:15:37
physical properties. So let’s immediately talk
00:15:39
about the properties of these substances, as I already
00:15:42
mentioned, molecules in a molecular
00:15:45
crystal lattice are connected by very
00:15:47
weak interactions, therefore as a
00:15:49
rule, these are liquids or gases with very
00:15:52
low boiling and
00:15:54
melting points that do not conduct
00:15:56
electric current in their pure form and
00:15:59
are quite weak, let's
00:16:02
write this down. So the
00:16:04
first one
00:16:08
is usually a liquid or gas
00:16:13
2 because of these weak intermolecular
00:16:16
interactions, it is not quite strong
00:16:18
substances the
00:16:22
third, respectively, is that they do not
00:16:24
conduct electric current in their pure form
00:16:28
and the fourth, respectively, is their low
00:16:31
boiling and melting points,
00:16:32
again low due to these
00:16:34
weak bonds, a
00:16:41
small caveat Some of them
00:16:44
can conduct electricity, for example in
00:16:46
solutions or melts But about this we
00:16:49
will clearly talk to you about other
00:16:51
topics, now we will turn to the most
00:16:53
interesting question: how to determine a
00:16:56
substance with a molecular crystal
00:16:58
lattice; the most important and effective
00:17:00
method in this case is everyone’s favorite
00:17:03
method of exclusion. That is, if we look
00:17:05
at a substance and understand that it does not
00:17:07
belong to metal ionic and
00:17:10
atomic crystal lattice, then
00:17:12
it turns out accordingly. It has
00:17:13
the molecular type Kaer, let's prove
00:17:17
this with you using the example of carbon dioxide
00:17:19
CO2. So CO2 is not a metal,
00:17:22
some kind of sodium, chromium, iron
00:17:25
is not a metal and therefore does not
00:17:27
have a metal crystal
00:17:30
lattice, we immediately discard it in CO2 there are
00:17:33
no ionic bonds, as a rule, these are
00:17:35
bonds between metals and metals, which means they are also ionic in the
00:17:38
crystal lattice. It smells exactly the same here
00:17:40
and the third moment of this
00:17:42
substance is not in our small list
00:17:44
for the atomic crystal lattice. Yes,
00:17:49
we have there, let me remind you, graphite Diamond,
00:17:51
respectively, silicon Boron and so on
00:17:54
yes CO2 is in our list no, respectively,
00:17:57
CO2 does not belong to the atomic
00:18:00
crystal lattice, also if CO2 does not
00:18:04
have a metallic and atomic
00:18:07
crystal lattice. The only thing that,
00:18:09
in principle, the only option left
00:18:11
is the molecular Kaer, so by the
00:18:14
method of exceptions we have determined with you the
00:18:16
type of crystal lattice of CO2 there are
00:18:20
also two points to which I would like to
00:18:22
draw your special attention. The first is the
00:18:25
wonderful word structure, that is,
00:18:27
very often they say molecular
00:18:29
structure instead of molecular
00:18:31
crystal lattice they can say not
00:18:34
molecular structure This means that the
00:18:36
crystal lattice and smart
00:18:38
metallic or, respectively, atomic
00:18:40
but not molecular This is the first moment
00:18:43
two, the tests may also come across
00:18:45
such substances as, for example, fullerene c60
00:18:49
white phosphorus p4
00:18:54
and so on. These substances very much
00:18:57
remind us of graphite and diamond and,
00:19:01
accordingly, red black phosphorus,
00:19:03
which we have in the list with substances
00:19:05
having an atomic crystal
00:19:08
lattice, but actually
00:19:11
these are substances with molecular type of
00:19:13
crystal lattice Yes, they are similar But
00:19:16
they are not on our list, respectively.
00:19:19
Therefore, if they do not have an atomic crystal
00:19:22
lattice, they do not have an ionic and
00:19:24
metal lattice, only
00:19:26
the molecular one remains. Do not forget about our favorite
00:19:30
method of exclusion for today,
00:19:32
we have all fully discussed such a topic
00:19:35
as types of crystal lattices, it will
00:19:37
definitely be useful to you in the fourth
00:19:38
task of the Unified State Exam. But if you liked
00:19:40
this format, do not forget to leave
00:19:42
likes under this video, comments in order to
00:19:45
actually promote the promotion and
00:19:48
release of new videos and be sure to
00:19:50
Subscribe to our YouTube channel and
00:19:52
turn on the bell so as not to miss
00:19:53
further videos With you there was Anastasia
00:19:55
Mayer and bye-bye to everyone

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