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химия с нуля
егэ по химии
огэ по химии
химия на отлично
школьная химия
химическая связь
типы химических связей
атомная кристаллическая решетка
молекулярная кристаллическая решетка
ковалентная связь
ковалентная полярная связь
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электроотрицательность
химияснуля,
егэхимия,
огэхимия,
химиянаотлично,
химическаясвязь,
типыхимическихсвязей,
атомнаякристаллическаярешетка,
молекулярнаякристаллическаярешетка,
ковалентнаясвязь,
ковалентнаяполярнаясвязь,
ковалентнаянеполярнаясвязь,
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00:00:00
hello, we are continuing the topic of chemical
00:00:03
bonding and today we will look in detail at
00:00:05
how a covalent bond is formed and in
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what compounds it is realized. To
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understand how a covalent bond is formed,
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we will again have to remember the
00:00:15
electronic structure of an atom, because everything that
00:00:18
happens to atoms is directly related to the
00:00:21
structure of their external energy
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level, well and of course, as an
00:00:26
example, let’s consider a compound as much as chlorine; in
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this compound, a covalent bond will be realized;
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what is it like? To
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understand this, let’s remember what the external
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and electronic levels in a hydrogen and
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chlorine atom look like; a hydrogen atom contains only
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one electron and it is naturally located
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on one from the sublevels, that is, the first
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level is already the
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outer layer of chlorine for hydrogen, only 17 electrons
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of which 7 are located on the outer third
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level, if we look carefully we
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will see that hydrogen has a single
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electron and it is, of course, unpaired, and the
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chlorine atom has 7 electrons on the outer level
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of which 6 form three
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pairs, one electron remains without a pair,
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it is unpaired and we write graphically the
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electronic formulas for these atoms:
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one unpaired electron in hydrogen and
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one unpaired electron in chlorine,
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the remaining six electrons on the outer
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level form three pairs, how
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will a covalent
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bond be formed? We can see that before the completion of the
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outer level, the hydrogen atom
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lacks one electron, because the 1c sub
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level can contain a maximum of two
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electrons,
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and the first level consists of only 1c sub
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level, so for the first level to be
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completely filled, hydrogen must have
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two electrons 1, that is,
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one hydrogen electron is missing
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Chlorine has 7 electrons on the outer level and
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for it to be completely filled,
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one electron is also missing, if you
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add one more electron here it will be 8
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electrons,
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and what happens between these
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atoms, a common electron pair is formed between them,
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that is, each of the atoms provides for
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common use its unpaired
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electron and, most importantly, this common
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electron pair
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simultaneously belongs to both atoms, that
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is, it is a pair of electrons for the
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hydrogen atom and it is also a pair of
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electrons for the chlorine atom, so it
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turns out that the hydrogen atom now has
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two electrons and this is a completely
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filled outer level 1 that is, the
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hydrogen atom acquired a stable
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electronic configuration of the noble gas
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helium, and the chlorine atom now has 8
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electrons; it had seven and another one
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it took for use from the hydrogen atom;
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now it has a total of 8 electrons, and
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this is also the stable electronic
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configuration of the noble inert gas,
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that is, now the level of each atom is
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completely filled with electrons, it is in
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this state that the atoms are most active,
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so we remember that a covalent bond
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is always the formation of common electron
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pairs, a common electron pair belongs
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simultaneously to all the ataman who
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participated in their formation; in fact,
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one electron pair is one
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covalent bond, an
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electron pair in graphic in formulas
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they are represented by a dash, now we
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remember that a dash
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means one common electron
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pair, and as an example, consider the
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nitrogen molecule nitrogen molecules consists of
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two hydrogen and nitrogen atoms, of course
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we remember substances simple non-metals of
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molecular structure h2 n 2 o 2 fluorine 2
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chlorine 2 Bruce
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together 2 why do these substances not
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exist in the form of individual atoms, but
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form diatomic molecules? Again,
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this is due to the structure of their external
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energy level. Let’s consider what
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it looks like for a nitrogen atom; nitrogen at the
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external level has 5 electrons, since nitrogen
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is in group 5; all these
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we should already know the rules and patterns,
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and of these 5 electrons, 2 form a
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pair on 2s sublevels and three are
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unpaired,
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and accordingly, the second
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nitrogen atom will have the same situation if we
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draw graphic
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electronic formulas for nitrogen atoms, we
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can distribute the electrons in this
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way, here’s one a pair of electrons two from
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under the level and and contains 3 unpaired
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electrons since each nitrogen atom has
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only 5 electrons and it is obvious that before
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the level is completed, each nitrogen atom
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lacks 3 electrons, which means somewhere these
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three electrons need to be taken and that’s how
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each of the atoms nitrogen borrows these
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three electrons from a neighboring atom and what we
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get as a result is that between two
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nitrogen atoms,
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common electron pairs are simultaneously formed from perry and 1 2 and 3,
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respectively, all three electron pairs
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belong to the first nitrogen atom and
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now it has 8 electrons in total and the
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second nitrogen atom and it also has
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a total of 8 electrons, that is, the external
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levels of these atoms are completely filled, which
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means they are stable, and of course, since
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one electron pair is one
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covalent bond,
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one dash, then between two
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nitrogen atoms we will draw three dashes because
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three common electrons have been formed
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pairs and this means that in a nitrogen molecule
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between two nitrogen atoms there are 3
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covalent bonds,
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remember that a covalent bond is equal to the total
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electron pair, the number of electron pairs
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indicates the number of the bond,
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everything is very simple, I think that here you
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just need to remember what an electron
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pair is and how it is designated in
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graphical formulas, we will look at
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another example, a water molecule, what kind of bonds
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are formed here, again for this we
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need to remember what the outer energy level looks like
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in an oxygen atom on the
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outer level oxygen has 6 electrons,
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4 of them form two pairs
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and two electrons remain unpaired and
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we In this way we denote two pairs of
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electrons and two unpaired electrons, a
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total of 6 electrons at the outer level,
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and each hydrogen atom, of course, has
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one unpaired electron; oxygen
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lacks two electrons to complete
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the level,
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and each hydrogen lacks one
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electron, so two hydrogens per
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atom oxygen form
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common electron pairs and we remember that a
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common electron pair
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is called common because it simultaneously
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belongs to one atom
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and in the second case, a water molecule, oxygen
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formed two common pairs with two
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hydrogen atoms, now oxygen has a total of 8
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electrons on the outer level and each
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hydrogen has formed one electron
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and a
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common electron pair with an
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oxygen atom, and now each hydrogen has
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two electrons on the outer level and also the
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outer level is the first and only one in the
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hydrogen atom is filled completely in
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this state, of course the atoms will be
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stable, so the covalent bond is
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quite strong, these are the common
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electron pairs they are
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atoms are very firmly connected to each other,
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and how does this
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bonding occur
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and what, in principle, is a
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covalent bond? the nucleus of the oxygen atom is
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naturally charged positively like
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all the nuclei of all other atoms,
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so the positive oxygen nucleus
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will attract negative
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electrons of hydrogen due to this
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its own image,
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this is an electron pair, these
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hydrogen electrons are attracted by the oxygen nucleus,
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and the hydrogen nuclei attract
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oxygen electrons, that is, it turns out that these
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electron shells seem to penetrate
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one another precisely due to the
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attraction of the electrons of the neighboring
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poison atom and the atomic nuclei,
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that is, you need to clearly understand what is a
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covalent bond? This is a type of
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electrostatic interaction in
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which the nucleus of one atom
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attracts the electrons of another atom. And
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of course, if we graphically depict a
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water molecule, we understand that we have
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formed two common electron pairs and
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one each between two hydrogen and
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oxygen atoms, which means 2 covalent bonds depart from oxygen,
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and oxygen
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formed two pairs,
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one covalent bond departs from each hydrogen, and
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each hydrogen
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participates in the formation of only one
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common electron pair. Well, let’s remember
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what a covalent bond is, this is an
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electrostatic interaction, we remember
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what electrostatic
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interactions are when plus attracts
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minus, this is the electrostatic
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interaction between the positive nucleus of
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one atom and the negatively charged
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electrons of another atom, this is a
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covalent bond, the most important thing we
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must remember is that a covalent bond
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is always the formation of shared electron
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pairs, the
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number of bonds depends on the number of shared
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electron pairs
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if the pair is 1 pi -bond 1 if part 2 to and
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bonds and two and so on the next thing we will
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consider regarding the covalent bond is
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also to find out in which compounds it
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is realized, so the covalent bond
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is realized only between
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metal atoms if before we considered the
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metallic bond and said that it
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arises only between metal atoms
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and identical metal atoms, that
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is, a
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metallic bond does not arise between all alme atoms, then a
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covalent bond arises precisely
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only between non-metal atoms, and
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based on this, a covalent bond is also
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further divided into polar
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and non-polar, how can we distinguish them?
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molecules consisting
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only of non-metal atoms, of course,
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this bond is covalent, there
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will be no other way, but how to understand in which case it is
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polar and in which case it is non-polar,
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so a polar covalent bond
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arises between atoms with different
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electronegativity, they are polar
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between atoms with the same, so what
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electronegativity is something you need to
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remember well because this is a
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very important parameter characterizing
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atoms electronegativity is the
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ability of an atom to shift a common
00:11:45
electron pair towards itself, of course, the higher the
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electronegativity values, the
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stronger it is, and then it pulls over
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this common pair of electrons, which
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was formed as a result of the interaction of
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atoms, well,
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there are tables that
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already indicate specific numerical values ​​of
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electronegativity, for example, here is a
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table of electronegativity from
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NGU where for each element of the main
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subgroup the numerical value of
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electronegativity is indicated, we can see
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that fluorine has the highest
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electronegativity equal to 4, which
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means that fluorine
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will always displace the electron
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pair by No one
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will ever be able to
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take away this electron pair from fluorine because fluorine has the
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highest electronegativity
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and electronegativity is precisely the
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ability of an atom to shift a
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common electron pair towards itself, and if we
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look carefully at this plate we
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will see such a pattern in the periods
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electronegativity will be
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increase from left to right,
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that is, when moving from metals to
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metals, and we can draw such an important
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conclusion that for mid
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olaf the electronegativity will be
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minimal and for her metals it will be
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maximum in each period in groups
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electronegativity increases
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from bottom to top, that is, of all the halogens of the
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elements of the seventh group of the main
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subgroups, the highest
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electronegativity will be for fluorine,
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the lowest electronegativity
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will be for as to the so even if
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we don’t have a tablet indicating the
00:13:30
electronegativity values, we
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can use the usual
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periodic table, but we must
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remember exactly this
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pattern of how
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electronegativity changes in periods and
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groups and let’s look at an example: in
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periods, electronegativity always
00:13:47
increases from left to right from metal to
00:13:51
metal, and in groups it always
00:13:53
increases from bottom to top, you need to
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remember this important rule very well,
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and now that we know what the
00:14:02
electronegativity of an atom is and how it
00:14:05
changes for different elements in a period
00:14:10
and in a group we can divide a
00:14:12
covalent bond into polar and non-
00:14:15
polar, for this we need to understand
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that a polar covalent bond
00:14:22
is realized between non-metal atoms with
00:14:26
different electronegativity there is a
00:14:30
covalent bond it is always a bond between
00:14:32
non-metal atoms but these non-metals
00:14:35
can have the same electronegativity values but
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they can have different ones, so if a bond
00:14:42
has arisen between non-metal atoms with
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different electronegativity, it
00:14:46
will always be a covalent polar bond, why is it
00:14:49
called that, what
00:14:51
happens in a molecule when
00:14:53
such a bond is formed, let’s also consider an example
00:14:57
and, as an example, consider a molecule
00:14:58
as much as chlorine, we have already discussed in at the beginning that in the
00:15:01
chlorine molecule one common
00:15:04
electron pair is formed, well, we understand that the
00:15:07
bond is covalent because it
00:15:09
was formed between two
00:15:12
non-metallic atoms hydrogen is not a
00:15:14
metal and chlorine is not a metal one pair means
00:15:17
this is one covalent bond,
00:15:20
naturally it will be polar and because
00:15:23
and and formed this connection of 2
00:15:26
non-metallic elements with different
00:15:29
electronegativity me if we
00:15:31
look at the
00:15:32
electronegativity table we will see that the
00:15:34
electronegativity of chlorine is
00:15:37
greater than the electronegativity of
00:15:39
hydrogen and this means that chlorine will
00:15:41
shift the common electron pair towards itself,
00:15:45
that is, it will move it away from hydrogen
00:15:48
and how this pair will approach to the
00:15:52
chlorine atom,
00:15:53
what is happening here is the most important thing,
00:15:57
taking into account the fact that
00:16:01
one extra electron is moving towards the chlorine atom, which was initially neutral, this is a
00:16:04
hydrogen electron, even if it
00:16:06
was not initially in the chlorine, but now it has moved towards the chlorine
00:16:09
since the electron carries a
00:16:11
negative charge in the tones a
00:16:14
partial negative charge appears
00:16:17
and on hydrogen it is partial positive,
00:16:20
this is important to remember if a covalent
00:16:23
bond is formed by non-metal atoms with different
00:16:27
electronegativity, that pair of
00:16:29
electrons
00:16:30
in common always shifts to a more
00:16:34
electronegative atom and a
00:16:36
partial negative charge always appears on it,
00:16:39
and the atom from which the pair
00:16:42
has moved away receives a partial
00:16:44
positive charge, why are these charges
00:16:48
partial they are designated delta plus
00:16:50
and delta minus because the electron does not
00:16:53
completely transfer from hydrogen to chlorine,
00:16:56
it’s not that hydrogen gave up one minus and
00:16:59
became one plus, and chlorine took one
00:17:02
minus and became one minus
00:17:05
charge, chlorine got one minus, it’s not so
00:17:08
important to remember the
00:17:10
electron does not completely transfer to chlorine,
00:17:12
it still simultaneously belongs to its
00:17:15
hydrogen
00:17:16
and chlorine, all this pair belongs to its
00:17:18
people and chlorine, but taking into account the fact that all the
00:17:21
same electrons have moved to chlorine, then a
00:17:24
negative cloud appears on it, a
00:17:29
negative electron density
00:17:32
increases on the chlorine atoms and this is possible
00:17:35
consider the example of such
00:17:38
graphic images, that is, when in
00:17:40
one molecule, and this is still one
00:17:42
molecule, a
00:17:47
negative charge is formed on one pole and a
00:17:49
positive charge is concentrated on the other pole,
00:17:52
such a molecule is called a dipole, that
00:17:55
is, we have two poles, plus and minus,
00:17:57
and since these poles 2 hence
00:18:00
the name de
00:18:01
these are two fields from the word pole dipole and
00:18:05
so molecules
00:18:07
containing covalent polar bonds
00:18:10
are always dipoles
00:18:12
and you can see how the
00:18:14
electron density is distributed in
00:18:16
such a molecule we are told that the common
00:18:19
electron pair of the
00:18:21
opar is the electron density,
00:18:23
that is, the
00:18:24
concentration of electrons shifts to the
00:18:27
more electronegative chlorine, a
00:18:30
partial
00:18:33
negative charge appears on chlorine, and on hydrogen,
00:18:35
since electrons have moved away from it, a
00:18:37
partial positive charge arises, the
00:18:40
value of this charge is always greater than 0, well,
00:18:43
less than one, because if suddenly
00:18:45
the charge becomes equal to one, this means
00:18:48
that the electron has completely transferred from the
00:18:51
hydrogen atom This does not happen to the chlorine atom in covalent
00:18:54
polar compounds; the
00:18:57
electrons are not completely transferred but are
00:18:59
simply partially displaced, but at the same time the
00:19:02
electron pair still
00:19:05
belongs to both
00:19:06
hydrogen and their chlorine. I hope that
00:19:08
this is clear, that is, a covalent
00:19:11
polar bond always occurs between
00:19:14
different
00:19:17
non-metal atoms different precisely in
00:19:20
electronegativity, and examples in
00:19:23
which compounds a
00:19:26
covalent polar bond can be realized, firstly in
00:19:29
acidic oxides,
00:19:30
most oxides are a combination of
00:19:34
oxygen with non-metals,
00:19:36
and we know that a covalent bond is
00:19:39
just a bond between non-metals, for example co2
00:19:42
is an acid oxide,
00:19:44
carbon monoxide and carbon and oxygen
00:19:46
non-metals but 1 2 not metals means there is
00:19:49
definitely a covalent bond between them,
00:19:51
well since these non-metals are different it means there is a
00:19:53
covalent polar bond between them the same
00:19:56
thing in a water molecule in a molecule as much as chlorine
00:19:59
in an ammonia molecule and nitrogen and hydrogen
00:20:01
are not a metal and they are different in
00:20:04
electronegativity means between they
00:20:06
create a covalent polar bond, a
00:20:09
covalent non-polar bond
00:20:11
is realized between non-metal atoms with
00:20:15
the same electronegativity, we can
00:20:19
consider examples phosphorus chlorine hydrogen
00:20:22
sulfur oxygen these are either substances of atomic
00:20:26
structure or substances of molecular
00:20:27
structure, but the most important thing is that in the composition of
00:20:30
these substances there are
00:20:31
only one type of non-metal atoms and
00:20:35
how is it distributed here electron
00:20:39
pair electron density
00:20:41
we understand that both atoms in a molecule of,
00:20:44
for example, hydrogen or chlorine are absolutely the
00:20:46
same, which means that their
00:20:49
electronegativity is absolutely the
00:20:51
same, which means that none of the
00:20:54
atoms can pull over this
00:20:56
common electron pair
00:20:57
and it seems to remain in the middle between
00:21:00
two atoms, and if the pair does not shift,
00:21:03
then no
00:21:06
partial charges arise on the atoms, and
00:21:09
if no charges arise, then a
00:21:11
dipole is not formed, that is, there is no polarity,
00:21:15
and if there is no polarity, then the bond is
00:21:17
covalent, nonpolar, I think everything here is
00:21:19
very logical and simple, well Using a
00:21:24
graphic example, we can consider that the
00:21:26
electron densities
00:21:28
in the case of the formation of a covalent
00:21:31
nonpolar bond are distributed
00:21:34
very evenly and there is no
00:21:37
obvious shift to one side
00:21:40
because the atoms are the same and none of them
00:21:42
can pull this electron pair over themselves.
00:21:45
In which compounds is a
00:21:48
covalent bond realized? non-polar bond in all
00:21:51
simple substances of non-metals, it doesn’t matter if it’s not a
00:21:54
metal of atomic structure or not a metal of
00:21:56
molecular structure,
00:21:58
if this simple substance is not a metal,
00:22:01
it means it consists of atoms of only
00:22:04
one type and
00:22:06
of atoms of non-metals, and this is exactly the
00:22:09
option when a covalent
00:22:12
non-polar bond is realized,
00:22:13
that is, if this is a bond between non-metals,
00:22:16
this bond is covalent, if between
00:22:18
identical non-metals and in simple
00:22:20
substances they can only be the
00:22:21
same, then this is a covalent
00:22:24
non-polar bond,
00:22:26
I really hope that everything is clear here,
00:22:28
if it is not clear, you can ask
00:22:30
additional questions in the comments,
00:22:31
we will analyze it further, but you just need to
00:22:34
listen carefully, concentrate and
00:22:36
find out what a covalent bond is,
00:22:39
and the last thing we will talk about is what
00:22:43
crystal lattices are realized in
00:22:45
substances with a covalent bond; substances
00:22:48
with a covalent bond, we remember, there are both
00:22:52
atomic structure and molecular
00:22:55
structure; examples of substances of atomic
00:22:58
structure are simple substances non-metals
00:23:00
phosphorus sulfur silicon carbon and so in
00:23:04
crystalline in a lattice of substances with a
00:23:08
covalent bond of
00:23:09
atomic structure, substances of atomic
00:23:12
structure, at the lattice nodes there will be
00:23:15
individual neutral atoms,
00:23:18
this is, for example,
00:23:20
the crystal lattice of diamond, and this is the
00:23:24
crystal lattice of graphite, and here and
00:23:27
there at the lattice nodes there are only
00:23:30
carbon atoms, just a different
00:23:33
geometric arrangement of these atoms,
00:23:36
which is why diamond has and graphite have such
00:23:38
different physical and chemical properties,
00:23:40
but in general these are simple substances consisting
00:23:43
only of carbon atoms, naturally,
00:23:46
if a bond occurs between
00:23:48
non-metal atoms, carbon is not a metal, this
00:23:50
bond is covalent, well, taking into account the fact that
00:23:52
these atoms are absolutely identical in
00:23:55
electronegativity, this bond is
00:23:57
covalent, non-polar in substances
00:24:02
molecular structure, of course, at the
00:24:05
lattice sites there will be molecules,
00:24:08
for example, diatomic molecules chlorine 2 ooo
00:24:12
2
00:24:13
h2 n2 at the lattice sites these diatomic molecules are located,
00:24:18
here is another example, at the
00:24:21
lattice sites of water there will
00:24:23
be 3 atomic water molecules, that
00:24:26
is, we remember that there are three
00:24:29
types of bonds metallic covalent and
00:24:32
ionic which we will look at in the next
00:24:34
lesson and
00:24:36
there are 4 types of crystal lattices metallic
00:24:40
characteristic only for metals atomic
00:24:43
and molecular characteristic of substances with a
00:24:47
covalent bond and
00:24:49
ionic characteristic of course for
00:24:52
substances ionic bonds in more detail about the ionic
00:24:56
bond and the ionic crystal lattice
00:24:58
we We’ll talk in the next lesson,
00:25:00
but that’s all for today, if you still have
00:25:02
any questions, be sure to ask in
00:25:04
the comments, don’t forget to subscribe to the
00:25:06
channel and like

Description:

В этом уроке ты узнаешь, что такое химическая связь между атомами и почему она возникает. Существует три основных типа химической связи - металлическая, ковалентная, ионная. Ковалентная связь бывает полярной и неполярной.

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