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Download "Урок 168. Задачи на вычисление внутренней энергии"

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Термодинамика
Молекулярная физика
Работа
Решение задач
Ришельевский лицей
Internal Energy
Thermodynamics (Field Of Study)
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00:00:14
today we spend the whole day solving problems in the
00:00:17
first lesson the topic will be problems on
00:00:20
calculating internal energy in the
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next lesson we will be doing
00:00:24
calculations with work and so the topic is problems on
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calculating internal energy problems on
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calculating internal energy
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homework on both sides at once for tomorrow
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kirik for 10th grade problems and with numbers 2
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3 4 2 3 4 of a sufficient level page
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39
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then according to Savchenko problem number 5 6 6 and
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problem number 56 15:05 615
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two additional words about this problem there you will need to
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calculate the energy in an isothermal
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process during isothermal expansion,
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in fact there is a formula which
00:01:56
allows you to calculate this energy, but outside, a
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logarithm is used,
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which we have not studied yet, so we
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make a graph of the process and using the graph using the
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palette method,
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we find the work. If anyone is familiar with
00:02:10
logarithms, check your result.
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logarithm is how to find out the work in an
00:02:16
isothermal process, but I’m not
00:02:17
telling you yet, but if you will type in
00:02:21
work in an isothermal process in Google, it will
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give you a form
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with a logarithm and so this is according to the graph,
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but it will immediately be clear that you have
00:02:38
graphs as you calculated from it, and
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now let’s start with the problem Gelfgat and number
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423
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number 423 miles per year after turning on
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the heating, the air in the room was heated from a
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temperature of 7 degrees Celsius to a
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temperature of 27 degrees Celsius, how many
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times did the internal
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energy of the air contained in the room change
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after turning on the heating, the air in the
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room heated from a temperature of t 17
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degrees Celsius to a temperature t2 of 27
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degrees Celsius, how many times
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did the internal energy change the energy of the air
00:03:33
contained in the room, well, let's
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find the ratio y 2 divided by u1
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let's remember how
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internal energy is calculated, let's assume that
00:03:48
air is an ideal gas, it consists of
00:03:51
molecules of some kind, how many atoms are
00:03:54
in one molecule of air, in fact
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there are different molecules, but most of them
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of them these are n2 molecules,
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then in second place o2 molecules are
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diatomic molecules, so we can
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assume that air consists of two
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atomic molecules and therefore the number of degrees of
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freedom is 5 5 and we can calculate the
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internal energy using this formula in the
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general case, I will now write this form
00:04:22
here as a certificate of equals and secondly,
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the mass is divided by the molar mass rt
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or you can write it briefly equalized
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and secondly not so what do you think
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the room is a sealed vessel or not
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what your life experience tells you of
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course they are not sealed under the threshold of the door
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through the cracks in the windows air can escape
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from the room and enter it,
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if the room were hermetically sealed,
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then when we heat the air, the pressure
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would increase and since the area of,
00:05:12
for example, glass is very large, it might
00:05:13
even squeeze out the glass, but the
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air calmly leaves the room,
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this at first glance makes it difficult for us to
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solve problems because when the air
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heats up, expanding, it leaves the
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room and the mass of the air
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in the room changes or the
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number of molecules of the air
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in the room changes, but in fact, this
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circumstance, on the contrary, makes it easier for us to
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solve the problem
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if we recall, in addition to the formula
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for internal energy, the equation of the
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Perron Mendeleev stake and so on the one hand, y
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equals 5 second yurts
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for air, the number of degrees of freedom is equal to
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5, and on the other hand, the product of
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pressure and volume according to
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Mendeleev’s equation is equal to not if you
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now substitute this product
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newerth and here you get internal
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energy equals 5 second points. V.
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the room is not sealed therefore p
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equals p atmospheric
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dimensions of the room
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we will neglect the thermal expansion of the walls as
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the temperature increases v equals a constant, it
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follows that y one equals 5
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second n
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atmospheric in the room and y 2 equals
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5 second n atmospheric new room that
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is, y one equals u2 the internal
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energy of the air in the room has
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not changed, or if you asked the
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ratio of 2 divided by y one equals
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one, here is the answer, how does it happen that
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we heat the air, its internal energy does
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not change, why does this happen,
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where does the energy that was
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released, for example, due to the operation of the
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heating system, go?
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air decreased in the room
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like this, but for every mole the
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internal energy increased
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because the temperature became higher,
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just part of the air came out and it turns out
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that the internal energy of the
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air that left the room is
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exactly equal to the energy that was
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released during the operation of the heating
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system, and the internal energy of the
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air itself is the room that was like this and
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remains like this is a paradox
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by the way, this is the technique of joint
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use of the Perron Mendeleev stake equation
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and the formula for internal
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energy very often we will
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use when solving problems see
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now we will do this the
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next problem from the Savchenko problem book
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number 562
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and number 56
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2a Savchenko
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we solved problem 562 b there it
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was necessary to determine the internal energy of
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one kilogram of air
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and now the question is what is the internal
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energy in joules under normal
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conditions of one cubic centimeter of air and
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so on up to the feet volume 1 cubic centimeter
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we are talking about air
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conditions are normal under normal
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conditions what the pressure is equal to 10 5
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pascals, and the temperature, I don’t know, it will
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be needed, it won’t be needed, just in
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case, let’s write down for normal conditions
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273 kelvin, you can find the internal
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energy of air, air, diatomic
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molecules and equal to 5, just wondering
00:10:01
how much in one cubic centimeter of
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air is this piece like this such
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a volume of a check as this piece of chalk, we
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remember the standard formula y
00:10:13
equals and the second yurt we are given the volume and
00:10:21
pressure, it is immediately clear that here we also
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need to use the equation about the
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feather in the middle
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of it, namely pe ve equals the yurt again
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we replace this product with the
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product of volume and pressure and then
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we get y
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equals and second n in here is the working
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formula we calculate y equals 5 second
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by 10 in 5 pascals
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multiplied by 1 cubic centimeter and
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how many cubic meters is 10 minus 6
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migal rights 10 minus 6 cubic meters
00:11:13
equals pascal multiplied by
00:11:16
cubic meter this is joule means here
00:11:19
we have one 10 times 5 second, that
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is, 2 and a half 0.25
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joules, the energy is very modest, but if
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you take a kilogram of air, we
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calculated it, you get a very impressive
00:11:35
number, just a cubic centimeter is a
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very small volume,
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move on to the
00:11:50
next problem 567, also according to Savchenko
00:11:54
go to Savchenko 567 listen to
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the conditions of the problem in a long
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thermally insulated pipe between two
00:12:15
identical pistons of mass m each
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there is one mole of monatomic gas
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at a temperature t zero at the initial
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moment the velocities of the pistons are directed in
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one direction and are equal to 3 v and at
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what is the maximum temperature
00:12:32
the gas pistons heat up do not carry out
00:12:36
the mass of gas in comparison with the mass of the pistons,
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neglect, write down the brief conditions, let's
00:12:44
think about what is happening here, so between
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two identical pistons of mass emma
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there is one mole of monatomic gas and is
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equal to three at a temperature t zero at the
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initial moment of speed the pistons are
00:13:11
directed in one direction and are equal to 3 c
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and c yes what is the maximum temperature
00:13:21
the gas will heat up, let's just
00:13:29
designate this maximum
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temperature t make a drawing of a pipe
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in it there are two pistons 1 has a mass m 2 has
00:13:53
a mass and
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the pipe is smooth the pistons move in one
00:14:03
direction and one of the pistons has a speed
00:14:07
3 you and the other one c yes what the maximum
00:14:10
temperature the gas will heat up if both
00:14:14
pistons move, for example, to the right and the gas is
00:14:16
heated as a result of this process,
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then which of these two pistons has the greater
00:14:22
speed, which of them is the 3rd,
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the left one is 3, because heating
00:14:28
occurs as a result of compression, the
00:14:30
work is done by the pistons
00:14:33
above the gas this leads to an increase in
00:14:35
internal energy and therefore temperature,
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therefore this pistons have a speed of 3 in
00:14:41
this in
00:14:50
between the pistons there is gas at the initial
00:14:53
moment having a temperature t zero
00:14:55
here of this gas 1 mole what else is known well, in
00:15:02
fact,
00:15:07
we will show everything here gas molecules and so why does the
00:15:12
gas heat up?
00:15:14
If the gas heats up touch me, its
00:15:17
internal energy internal energy
00:15:19
can be changed in two ways either by
00:15:21
doing work on the gas or through
00:15:25
heat transfer,
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here, according to the conditions of the problem, everyone is
00:15:28
thermally insulated, which means the change in
00:15:31
internal energy occurs due to the
00:15:33
work done,
00:15:34
this work is done by pistons, they
00:15:37
move with at different speeds and the
00:15:40
left rear piston catches up with the front ones as
00:15:46
a result the gas is compressed, what can be
00:15:48
said about the speeds of the pistons when the gas
00:15:53
has a maximum temperature
00:15:56
Andrey it will be the same, will the
00:16:00
pistons touch at the same time, no, they
00:16:03
rush, so we understand with you that
00:16:07
when the distance between the pistons becomes
00:16:10
the smallest, the gas temperature will be
00:16:13
the largest, but if the distance has become
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the smallest, this means that both
00:16:18
pistons at this moment in time are moving at the
00:16:20
same speed,
00:16:21
let’s denote this speed with a stroke and show the
00:16:24
state of the system at this moment in time
00:16:31
pipe 2 pistons,
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the mass of each m, they have already approached,
00:16:41
each of them has a speed of stroke
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it is not difficult to guess that this one will slow down
00:16:51
into a stroke and this one will accelerate due to the
00:16:55
gas pressure, there is a compressed gas at a
00:17:02
temperature t which you need to find something to
00:17:09
catch on the work that the pistons do
00:17:14
on the gas due to what it is
00:17:18
done because any work is
00:17:20
done due to energy due to the
00:17:24
kinetic energy of the pistons this means
00:17:29
how much the kinetic energy of the pistons has decreased, the
00:17:32
internal
00:17:36
energy of the gas will increase, and why is it not necessary to take into
00:17:40
account the fact that the gas itself is ordered and
00:17:43
moves along with the pistons; it does not
00:17:45
just move chaotically, but in general the entire
00:17:48
mass of gas also rushes along with the
00:17:50
pistons; why is this contribution not needed?
00:17:52
take into account the kinetic energy, let's
00:17:58
also read the conditions of the problem with the mass of the gas
00:18:00
compared to the mass of the piston, neglect
00:18:03
that is, we assume that the gas is so small
00:18:06
that its contribution to the total kinetic
00:18:09
energy is negligible, then we can write the
00:18:14
kinetic initial
00:18:18
minus and the kinetic prime and the
00:18:22
kinetic 0 minus and the kinetic
00:18:24
simply without a primer like this this is what is this
00:18:29
how much has the kinetic energy decreased
00:18:32
so much the
00:18:34
internal
00:18:36
energy in the case has increased so now let's
00:18:42
look at all this in detail and the
00:18:45
kinetic zero
00:18:46
initial reserve the kinetic energy of the pistons
00:18:49
is the kinetic energy of this
00:18:51
piston plus the kinetic energy of this
00:18:53
guy this will be emma at 3 v squared in
00:18:59
half plus m squared in half
00:19:08
equals 9 plus 110
00:19:14
equals 5 m squared is the reserve of
00:19:19
kinetic energy of both pistons at the
00:19:21
beginning at the end and the kinetic equals
00:19:28
twice
00:19:29
since there are 2 pistons per m.v.
00:19:33
dash square in half 2 pistons each have
00:19:39
kinetic energy such as
00:19:41
we designated the speed as a dash, it
00:19:43
turns out equal to m in a dash square
00:19:49
internal energy
00:19:51
delta u equals the final value of the
00:19:56
internal energy minus the initial
00:19:58
of course this is when the temperature
00:20:01
is maximum that is, it will be a
00:20:04
monatomic gas three second not although there one
00:20:10
mole, but the dimension must be preserved,
00:20:12
so I write
00:20:15
yurt
00:20:17
minus the initial internal energy three
00:20:21
second yurts 0 and so
00:20:29
now we substitute all this here, we
00:20:35
get 5 m squared minus m a stroke
00:20:46
squared equals 3 second new era
00:20:51
three second is not a reproach
00:20:54
on p minus t zero what we
00:21:03
know here what we don’t know we are asked
00:21:05
to find t t 0 is not is mass is in is
00:21:11
missing wasd them
00:21:20
how can you find your stroke rods
00:21:27
smooth
00:21:28
pipe smooth pistons throats friction no
00:21:33
gravity can also be considered not clearly
00:21:45
arithmetic mean from wherever
00:21:47
it worked out but good yes they
00:21:55
interact with each other cass like a
00:21:58
spring before there are external forces acting between them
00:22:03
there is no what is the name of a
00:22:07
system that is not acted upon by external
00:22:09
forces closed for a closed system
00:22:14
some conservation laws are satisfied
00:22:17
you can call them the law of conservation of
00:22:21
momentum let's use the law of
00:22:24
conservation of momentum system the pistons are
00:22:26
closed, therefore the total momentum of the bodies
00:22:31
forming a closed system remains
00:22:33
unchanged for any interactions
00:22:35
between these bodies, here the interaction
00:22:37
occurs through the gas, the momentum of the gas is
00:22:39
neglected according to the conditions of the problem, the mass of the
00:22:41
gas is small, therefore we can write,
00:22:43
according to the law of conservation of momentum, 3 m in
00:22:51
this is the momentum of the first piston plus m.v .
00:22:56
this is the impulse 2 of the piston equals to prime
00:23:02
plus to r prime I don’t write vectors
00:23:09
because all the pistons move in one direction and
00:23:11
what is the ratio that connects the modules the
00:23:14
same ratio connects the projections onto the
00:23:16
axis from here the mass will be reduced and it turns out on the
00:23:22
left 4 in the right 2
00:23:26
prime that is, it turns out that a prime
00:23:31
equals simply 2 in the
00:23:34
arithmetic mean indeed
00:23:36
Andrey was right but this is his intuition, his
00:23:39
intuition told him now we
00:23:41
used the laws of conservation
00:23:42
of momentum,
00:23:43
we substitute here we get 5 m
00:23:49
squared minus m by 2 v squared
00:23:56
equals 3 second nes p-n t minus t 0
00:24:03
and here we have 4 mv square here 5 mv
00:24:09
square means we can write m squared
00:24:14
equals 3 second yurts minus t 0 all that
00:24:22
remains is algebra
00:24:31
from here we first find the parenthesis you
00:24:35
minus t zero equals 2m squared
00:24:42
divided by 3 by 3 new era 3 newer and the
00:24:49
last step is to find the
00:24:51
maximum temperature t equals t 0
00:24:57
+ 2 m squared divisor by 3 not a
00:25:07
problem solved numerical value
00:25:09
not required here this is how mechanics
00:25:13
interact with molecular physics
00:25:15
the laws of mechanics can be easily
00:25:17
used when solving problems at home
00:25:20
this problem
00:25:21
566 of the same type to a little simpler we
00:25:24
took it more difficult I will give a
00:25:27
simpler task is proposed the next task is
00:25:41
also Savchenko 5-6 4 number 5 6 4 Savchenko
00:25:54
something similar we have already encountered but
00:25:58
nevertheless this is a completely different
00:25:59
task in a vessel with a capacity
00:26:03
of one is located one there for gas at
00:26:06
pressure p1 and temperature t1 and in a vessel with
00:26:10
a capacity of 2
00:26:11
monatomic gas at pressure p2 and
00:26:14
temperature t2
00:26:15
what pressure and what temperature
00:26:18
will be in these vessels after they are
00:26:21
connected the vessels are thermally insulated so
00:26:25
we make two drawings
00:26:28
two vessels are connected to each other by a closed valve
00:26:45
here pressure p1
00:26:50
here volume of one temperature t one
00:26:55
valve is closed gas 1 there and and equals 3
00:27:02
then in a vessel of capacity 2 there is
00:27:08
also a monatomic gas at pressure p2
00:27:13
volume of 2
00:27:14
temperature t2 what pressure and what
00:27:20
temperature will be in these vessels
00:27:22
after they are connected the
00:27:35
valve is open
00:27:40
what can we say about the pressures on the left and
00:27:43
right?
00:28:05
we open the tap, thermal
00:28:09
equilibrium occurs if there are too many
00:28:11
fast molecules here and they don’t get here and
00:28:15
heat up the gas here in thermal
00:28:19
equilibrium the temperatures here will also be
00:28:21
the same you stroke here floor 3 here
00:28:24
and so we are given we are given p 1 in 1 p1
00:28:33
p2 in two t2 gas 1 tons and we need to find p
00:28:42
prime and t prime we had a similar
00:28:46
problem
00:28:47
but it was solved in a completely different way
00:28:50
because it was said that the temperature was the
00:28:53
same all the time, that is, there
00:28:56
the temperature did not change, but here the system is
00:28:59
thermally insulated then what is
00:29:01
preserved here if the system
00:29:03
thermally insulated internal energy
00:29:07
pistons here gas does not move
00:29:09
any work does not perform
00:29:12
thermal insulation ensures the absence of
00:29:15
heat transfer means the internal energy
00:29:18
remains the same so let's
00:29:21
denote the internal energy of this portion of
00:29:23
gas in one of this portion of gas u2 of
00:29:27
this portion of gas in one stroke of this
00:29:32
portion u2 stroke and Let's write according to the
00:29:36
conservation law for the
00:29:37
gene
00:29:44
y 1 plus 2 equals y one stroke plus
00:29:51
two strokes
00:29:54
then I remember the formulas for calculating the
00:29:56
internal energy we have such a
00:29:59
formula will equalize three second gas
00:30:02
one-ton yurt
00:30:07
there is another version that we have already
00:30:11
used twice this is not rt this is foam in
00:30:14
then we can write y equals the
00:30:19
second three pv which of these formulas is more convenient
00:30:25
to use the right right one because
00:30:28
we are given pressures and here and here and
00:30:33
here one unknown is also included, the
00:30:35
pressure at the end means we use the
00:30:37
right formula then as u1 we
00:30:40
write the three second p 1 in 1 plus u two three
00:30:49
second n 2 in 2 these all values ​​are known
00:30:54
equals 3 second n stroke in one plus
00:31:02
three second n dash 2
00:31:04
everything from here can be found by stroke by three
00:31:10
second divided term by term and you get p 1 v1 + p
00:31:17
2 in 2 equals here the prime can be
00:31:21
taken out of the bracket
00:31:23
here it will be one plus you barely
00:31:28
so the b-prime
00:31:35
equals the fraction in the numerator p 1 v1 + p 2
00:31:43
v2 divided by v1 + v 2 yes we
00:31:59
neglect the volume of this tube the
00:32:04
first part of the problem is solved
00:32:07
the law of conservation of energy we used
00:32:10
but the temperature we never found this
00:32:15
for it’s probably useless to use these formulas already
00:32:18
what can we do to
00:32:21
find the temperature
00:32:27
let’s use the law of conservation
00:32:30
of matter the total number of molecules here has
00:32:35
not changed the number of moles in this
00:32:39
vessel we denote not one here not u2
00:32:44
here not one stroke here not u2 prime
00:32:48
means we can write that no
00:32:52
plus me 2 equals no prime plus
00:32:56
her two primes
00:32:58
this is what we did when we were told that the
00:33:02
process is isothermal we needed to find the
00:33:04
pressure remember when we connected two vessels
00:33:06
now the
00:33:09
law of conservation of matter continues to work and now
00:33:17
let’s use by the Clapeyron
00:33:18
Mendeleev equation, namely pe ve equals not p
00:33:27
volume and pressure we already know everywhere,
00:33:31
which means we can somehow
00:33:34
express the temperature from here and so let’s
00:33:36
express from here the amount of substance does not
00:33:40
equal p in divided by
00:33:43
mouths now we use this formula
00:33:48
to record these four values ​​not u1
00:33:53
this will be p 1 in 1 divided by r t1 plus
00:34:02
not y 2 p 2 in 2 by r
00:34:09
t2 is equal to the right not really their pressure p
00:34:15
prime we know it if that on
00:34:19
in 1 divided by p a t prime + p prime on
00:34:29
v2
00:34:31
on rts stroke you stroke on r can
00:34:39
be shortened, we can write down what is left on the
00:34:48
left left n 1 in 1 divided by d1 plus
00:34:56
d2 in 2 divided by t2 on the right left
00:35:02
b-stroke divided by you stroke by the sum of
00:35:06
volumes I put it out of brackets in one plus
00:35:11
[ __ ] so now so that we don't have double
00:35:14
fractions double fractions let's
00:35:17
bring it to a common denominator here
00:35:19
we get p 1 in 1 t2 plus p 2
00:35:30
in 2d 1 divided by t1 and t2 equals
00:35:38
b-prime over r prime on v1 + v 2
00:35:45
from here we find a test of them
00:35:53
you the stroke is equal to then the stroke will go
00:35:58
here in the numerator and this whole fraction will go
00:36:02
to the right side with the numerator and
00:36:05
denominator changing places and so here we
00:36:07
will have a stroke multiplied by v1 + and v2
00:36:14
now this is all that will be here in the numerator
00:36:16
in the denominator p 1 in 1 t2 plus p
00:36:24
2 in two t1 and this t 1 t2
00:36:29
will go to the right in the numerator t1 and t2
00:36:35
this is not the answer yet because now we need to
00:36:38
substitute this stroke here,
00:36:44
then we will get that stroke equals
00:36:48
/ and this denominator p 1 in 1 t2 plus p 2
00:36:57
in two t1 then look when we
00:37:03
substitute primes in the numerator we
00:37:06
must write p 1 v1 + p 2 in 2 write
00:37:09
p 1 v1 + p 2 in 2 in the denominator we must
00:37:15
write in one plus in 2,
00:37:17
write it down here, but there is exactly the
00:37:20
same one in the numerator, they will cancel out,
00:37:23
so I won’t write anything except
00:37:27
m1 and m2, here is the answer
00:37:37
since the formula is cumbersome and does
00:37:40
not require us to do numerical calculations, let’s at
00:37:43
least check the dimension here we have
00:37:47
joules joules yes here joule multiplied
00:37:53
by kelvin plus joule multiplied by
00:37:56
kelvin joules will be reduced inverse
00:37:57
terms multiplied by kelvins squared
00:38:01
turns out in kelvins
00:38:03
well here you can immediately see that the answer
00:38:05
is obtained colleagues the problem is solved yes you do
00:38:16
n’t have to substitute this,
00:38:19
but by the way this is a lot for you if
00:38:21
you need to find a number you’re this
00:38:23
you can use the number and substitute it here,
00:38:25
in fact, it’s not very good for you and
00:38:28
will simplify the problem, all the same, when
00:38:31
we performed the substitution, this one was
00:38:33
reduced by one plus by 2, so we take a
00:38:36
break, then we solve the problems again

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Урок физики в Ришельевском лицее

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